Archive for March, 2010
Iranian Green Revolution Regime Change or The Iranian War–Sooner Rather Than Latter–Videos
Iranian Green Revolution
“Freedom is never voluntarily given by the oppressor; it must be demanded by the oppressed. “
~Martin Luther King, Jr.
Israel Does Not Need U.S. Permission To Attack Iran! John Bolton
Amb. John Bolton – Israel Gains Nothing By Waiting To Attack Iran
The case for the pre-emptive strike on Iran keeps looking stronger
John Bolton: Window Closing for Israeli Military Action Against Iran
US preparing military for possible war with Iran Jan. 9 2010
Flynt Leverett Debates Michael Ledeen on Iran Policy 3-3-10
Iranian Protesters Becoming More Aggressive! John Bolton MoxNewsDotCom
Israel Forcing U.S. To Attack Iran And Kill Millions
New CIA Report Says Iran Now Able To Produce Nuclear Weapons
War with Iran imminent, Bunker busters being deployed
final countdown israeli defence force
Massive Naval Exercise Underway Off US Coast In Possible
One morning you will wake up and hear on the news that Israel and/or the United States have destroyed Iran’s capability of producing nuclear weapons.
This news will be sooner rather than latter.
Better news would be that the Iranian people have toppled the current regime and want to stop Iran’s nuclear weapons program.
The who and when question will not be postponed indefinitely.
An Iranian regime with nuclear weapons is unacceptable to both the Israeli and American people.
Unfortunately, when it come to Iran, President Obama is in denial or naive.
After 31 years of killing American and Iranian citizens the time is long past due for regime change.
Regime change is much preferred to World War III.
Neither diplomacy nor sanctions have worked.
Time is running out and options are few.
Either support the Iranian people or have the United States and Israel armed forces take out the religious fanatics and their nuclear weapon facilities.
Yet President Obama talks and talks and talks–the Iranians are not listening and the Americans do not believe a word Obama says.
Keep listening to talk radio.
Either the Iranian Government falls or World War III begins.
Expect $10 a gallon gasoline prices or higher if the news is World War III.
“…THESE are the times that try men’s souls. The summer soldier and the sunshine patriot will, in this crisis, shrink from the service of their country; but he that stands by it now, deserves the love and thanks of man and woman. Tyranny, like hell, is not easily conquered; yet we have this consolation with us, that the harder the conflict, the more glorious the triumph. What we obtain too cheap, we esteem too lightly: it is dearness only that gives every thing its value. Heaven knows how to put a proper price upon its goods; and it would be strange indeed if so celestial an article as FREEDOM should not be highly rated. …”
~Thomas Paine, The American Crisis
Background Articles and Videos
Kissinger threatens Regime Change in Iran if coup fails…
War with Iran imminent, Bunker busters being deployed
Could Israel attack Iran?
2010 Mid-East New’s – Israel Poised And Ready To Strike Iran Soon!
IAEA Iran’s uranium enrichment fully supervised – PressTV
CrossTalk on Iran: Regime change crusade?
Related Posts On Pronk Palisades
Iranians Take Over Iraqi Oil Well and Dismiss US Nuclear Deal–Call Obama’s Bluff–Obama’s Response–Absolutely Nothing
Israel Prime Minister Netanyahu Speaks Truth To Evil and Power–Where Will The American People and President Obama Stand?
The Iranian Revolution and Regime–Videos
Time To Topple Totalitarians–Let Liberty Loose–Message From American People To Iranian People–We Support Your Quest For Freedom
Old Media–Deaf, Dumb, Blind, Silent, Irrelevant and Fading Fast
Israel Prime Minister Netanyahu Speaks Truth To Evil and Power–Where Will The American People and President Obama Stand?
Obama and Clinton Betray Allies and Appease Russia Over Proposed Missile Defense System Against Iranian Missile Nuclear Threat!
Remembering September 11, 2001 On The Eighth Anniversary
Failing The Iranian Test–Barack “Hamlet” Obama–To Be or Not To Be President of The United States And Commander-in-Chief?
The Planted Assumption of The National Intelligence Estimate On Iran’s Nuclear Weapons Program: Assumes It Conclusion–CYA From Partisan Authors!
The Coming Joint US and Israeli Military Offensive with Syria and Iran–Just Waiting for the Casus Belli?
World Wide War Warning–100 Day Countdown!
Read Full Post | Make a Comment ( None so far )Thomas E. Woods–The Catholic Church: Builder of Civilization–Videos
The Catholic Church: Builder of Civilization Episode 1 [Part 1]
The Catholic Church: Builder of Civilization Episode 1 [Part 2]
The Catholic Church: Builder of Civilization Episode 1 [Part 3]
The Catholic Church Builder of Civilization, The Church and Science Ep 2 [Part 1]
The Catholic Church Builder of Civilization, The Church and Science Ep 2 [Part 2]
The Catholic Church Builder of Civilization, The Church and Science Ep 2 [Part 3]
The Catholic Church: Builder of Civilization, Priests as Scientific Pioneers Ep. 3 [Part 1]
The Catholic Church: Builder of Civilization, Priests as Scientific Pioneers Episode 3 [Part 2]
The Catholic Church: Builder of Civilization, Priests as Scientific Pioneers Episode 3 [Part 3]
The Catholic Church: Builder of Civilization – The Galileo Files, Ep. 4 [Part 1]
The Catholic Church: Builder of Civilization – The Galileo Files, Ep. 4 [Part 2]
The Catholic Church: Builder of Civilization Episode 4 [Part 3]
The Catholic Church: Builder of Civilization – The University System, Ep 5 [Part 1]
The Catholic Church: Builder of Civilization – The University System, Ep 5 [Part 2]
The Catholic Church: Builder of Civilization Episode 5 [Part 3]
The Catholic Church: Builder of Civilization – Does God Exist? Ep. 6 [Part 1]
The Catholic Church: Builder of Civilization – Does God Exist? Ep. 6 [Part 2]
The Catholic Church: Builder of Civilization – Does God Exist? Ep. 6 [Part 3]
The Catholic Church: Builder of Civilization – The Monks, Ep. 7 [Part 1]
The Catholic Church: Builder of Civilization – The Monks, Ep. 7 [Part 2]
The Catholic Church: Builder of Civilization – The Monks, Ep. 7 [Part 3]
The Catholic Church: Builder of Civilization – Catholic Charity, Ep 8 [Part 1]
The Catholic Church: Builder of Civilization – Catholic Charity, Ep 8 [Part 2]
The Catholic Church: Builder of Civilization – Catholic Charity, Ep 8 [Part 3]
The Catholic Church: Builder of Civilization – Western Morality, Ep. 9 [Part 1]
The Catholic Church: Builder of Civilization – Western Morality, Ep. 9 [Part 2]
The Catholic Church: Builder of Civilization – Western Morality, Ep. 9 [Part 3]
The Catholic Church: Builder of Civilization – The Concepts of Rights and Law, Ep. 10 [Part 1]
The Catholic Church: Builder of Civilization – The Concepts of Rights and Law, Ep. 10 [Part 2]
The Catholic Church: Builder of Civilization – The Concepts of Rights and Law, Ep. 10 [Part 3]
The Catholic Church: Builder of Civilization – The Origins of International Law, Ep. 11 [Part 1]
The Catholic Church: Builder of Civilization – The Origins of International Law, Ep. 11 [Part 2]
The Catholic Church: Builder of Civilization – The Origins of International Law, Ep. 11 [Part 3]
The Catholic Church: Builder of Civilization – The Origins of International Law, Ep. 12 [Part 1]
The Catholic Church: Builder of Civilization – The Origins of International Law, Ep. 12 [Part 2]
The Catholic Church: Builder of Civilization – The Origins of International Law, Ep. 12 [Part 3]
The Catholic Church: Builder of Civilization – Series Recap Ep. 13 [Part 1]
The Catholic Church: Builder of Civilization – Series Recap Ep. 13 [Part 2]
The Catholic Church: Builder of Civilization – Series Recap Ep. 13 [Part 3]
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G. William Domhoff: Who Runs America–Videos
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G. Edward Griffin- On Individualism vs. Collectivism–Videos
Mark Levin–Liberty and Tyranny: A Conservative Manifesto–Videos
George Gerald Reisman–Why Nazism Was Socialism and Why Socialism Is Totalitarian–Videos
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President Barack Obama’s Role Model–President Franklin D. Roosevelt–The Worse President For The U.S. and World Economies and The American People–With The Same Results–High Unemployment Rates–Over 25 Million American Citizens Seeking Full Time Jobs Today–Worse Than The Over 13 Million Seeking Jobs During The Worse of The Great Depression!
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Read Full Post | Make a Comment ( None so far )Mike MOSER, Lewis J FELDMAN, Craig MORITZ, Vincent H. RESH–Biology 1B–University of California, Berkeley–Videos
University of California, Berkeley, Online Course
http://webcast.berkeley.edu/courses.php
Biology 1B, 001 – General Biology
MWF 8-9 | 2050 VALLEY_LSB
Instructor Mike MOSER, Lewis J FELDMAN, Craig MORITZ, Vincent H. RESH
General Biology
Biology 1B – Lecture 1: Introduction / Fungi
Biology 1B – Lecture 2: Algae, Mosses, Lower Vascular Plants
Biology 1B – Lecture 3: Ferns and Gymnosperms
Biology 1B – Lecture 4: Angiosperms
Biology 1B – Lecture 5: Angiosperms
Biology 1B – Lecture 6: Cells, Tissues
Biology 1B – Lecture 7: Roots, Structure and Development
Biology 1B – Lecture 8: Shoots, Primary Structure
Biology 1B – Lecture 9: Shoots, Secondary Structure
Biology 1B – Lecture 10: Plant Growth Substances 1
Biology 1B – Lecture 11: Plant Growth Substances 1
Biology 1B – Lecture 12: Flowering
Biology 1B – Lecture 13: Water Relations
Biology 1B – Lecture 14: Water Relations, Mineral Nutrition,
Biology 1B – Lecture 15: Relevance and history
Biology 1B – Lecture 16: Plant Growth Substances 1
Biology 1B – Lecture 17: The tree of life: Phylogeny
Biology 1B – Lecture 18: Population processes – inheritance,
Biology 1B – Lecture 19: Mutation and selection – theory, ex
Biology 1B – Lecture 20: Genetic drift and migration – theor
Biology 1B – Lecture 21: Recombination, sexual reproduction
Biology 1B – Lecture 22: Sexual selection – coevolution
Biology 1B – Lecture 23: Species concepts, – reprod isolatio
iology 1B – Lecture 24: Speciation processes (cont)
Biology 1B – Lecture 25: Fossil record – macroevol trends –
Biology 1B – Lecture 26: Fossils, evo-devo and evolution of
Biology 1B – Lecture 27: Human evolution and evolutionary me
Biology 1B – Lecture 28: Plant Growth Substances 1
Biology 1B – Lecture 29: Plant Growth Substances 1
Biology 1B – Lecture 30: Plant Growth Substances 1
Biology 1B – Lecture 31: Plant Growth Substances 1
Biology 1B – Lecture 32: Plant Growth Substances 1
Biology 1B – Lecture 33: Plant Growth Substances 1
Biology 1B – Lecture 34: Plant Growth Substances 1
Biology 1B – Lecture 35: Plant Growth Substances 1
Biology 1B – Lecture 36: Plant Growth Substances 1
Biology 1B – Lecture 37: Plant Growth Substances 1
Biology 1B – Lecture 38: Plant Growth Substances 1
Biology 1B – Lecture 39: Plant Growth Substances 1
Biology 1B – Lecture 40: Plant Growth Substances 1
Biology 1B – Lecture 41: Plant Growth Substances 1
Biology 1B – Lecture 42: Plant Growth Substances 1
Biology 1B – Lecture 43: Plant Growth Substances 1
Biology 1B – Lecture 44: Plant Growth Substances 1
Natural Sciences
Biology
Gary L. FIRESTONE, Michael MEIGHAN, Jasper D. RINE, Jennifer A DOUDNA–Biology 1A–University of California, Berkeley–Videos
Marian Diamond–Integrative Biology 131: General Human Anatomy. Fall 2005. –University of California, Berkeley–Videos
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Philosophy
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Read Full Post | Make a Comment ( None so far )Fox News, Google, Glenn Beck, Barack Obama–Who Is Deleting Videos of Glenn Beck Shows On YouTube?
I recently noticed that a number of YouTube accounts that routinely had clips of the Glenn Beck show were now suspended:
This account is suspended.
Also, several of the videos were no longer available:
This video is no longer available due to a copyright claim by Fox News Network, LLC.
The only time I see Glenn Beck’s show is on YouTube.
I do not watch television.
I routinely use Glenn Beck clips in my blog posts.
Here is just one example of what is happening:
Glenn Beck On Prosperity And The Perils of Progressivism
If Fox News or Glenn Beck are responsible, I strongly suggest they reconsider.
If Google or YouTube are doing this to keep the Glenn Beck show off of YouTube, both Glenn and Fox need to complain.
I would not be surprised if the White House complained to its supporters at Google to have these video clips deleted.
Glenn, I suggest you have this checkedout and the videos reposted on YouTube.
Otherwise, I will no longer be featuring your show on my blog; and for all practical purposes Obama was successful in getting you off other new media blogs as well.
PS
Upon further reflection, I have concluded that someone at Fox News has their head up their ass, otherwise YouTube would not have stated they were the reason the clips were deleted.
News Flash to Fox News. You are shooting your own talent in the foot.
This is real dumb.
The blogs both good, bad and ugly promote shows like Beck and Hannity.
This is free promotion.
If Glenn Beck show clips are no longer on YouTube, I will no onger be posting his shows to potential readers of my blog and they in turn will not be watching or listening to Glenn Beck.
Looks like the same idiots that run the other major networks whose viewership has steadly decined are running Fox News.
Old media simply does not get new media.
Most young people do not read newspapaers and less and less watch television.
Get a clue as to where they go for their news and other information–online or the web.
Wake up Glenn and rattle some cages at Fox News.
Read Full Post | Make a Comment ( None so far )
Gary L. FIRESTONE, Michael MEIGHAN, Jasper D. RINE, Jennifer A DOUDNA–Biology 1A–University of California, Berkeley–Videos
Biology 1A, 001 – General Biology Lecture
MWF 8-9 | 1 PIMENTEL
Instructor Gary L. FIRESTONE, Michael MEIGHAN, Jasper D. RINE, Jennifer A DOUDNA
Biology with Mastering Biology (8th Edition)
Neil A. Campbell/Jane B. Reece
$135
Student Study Guide for Biology (Paperback)
Neil A. Campbell (Author)
Jane B. Reece (Author)
Martha R. Taylor (Author)
$57
http://webcast.berkeley.edu/course_details_new.php?seriesid=2010-B-7703&semesterid=2010-B
Biology 1A – Lecture 1
Biology 1A – Lecture 2: Structure and function: lipids, carbohydrate and nucleic acids
Biology 1A – Lecture 3: Cell structure and organization -#1
Biology 1A – Lecture 4: Cell structure and organization -#2
Biology 1A – Lecture 5: The structure of biological membranes
Biology 1A – Lecture 6: Cellular metabolism and biological c
Biology 1A – Lecture 7: Enzyme structure
Biology 1A – Lecture 8: Regulation of enzymatic activity
Biology 1A – Lecture 9: Introduction to bioenergetics
Biology 1A – Lecture 10: Cellular energy production and anae
Biology 1A – Lecture 11: Cellular energy production and aero
Biology 1A – Lecture 12: Photosynthesis-the light reactions
Biology 1A – Lecture 13: Photosynthesis-CO2 fixation and rel
Biology 1A – Lecture 14: I, PCR. Microbial Genetics and Evo
Biology 1A – Lecture 15: DNA Replication and the PCR
Biology 1A – Lecture 16: Cell Cycle, Mitosis and Reproduction
Biology 1A – Lecture 17: Chromosomes, Checkpoints, and Cancer
Biology 1A – Lecture 18: Meiosis and Sexual Life Cycle
Biology 1A – Lecture 19: Gregor Mendel and 2 of Biologys 3 L
Biology 1A – Lecture 20: Recombination, Linkage and Mapping
Biology 1A – Lecture 21: Transcription
Biology 1A – Lecture 22
Biology 1A – Lecture 23: Prokaryotic Gene Regulation
Biology 1A – Lecture 24: Eukaryotic Gene Expression and Regulation
Biology 1A – Lecture 25: Human Genetics and Epigenetics
Biology 1A – Lecture 26:
Biology 1A – Lecture 27: Multi-cellularity: Cell Shape and f
Biology 1A – Lecture 28: Intercellular and Physiological Com
Biology 1A – Lecture 29: Intercellular and Physiological Com
Biology 1A – Lecture 30:
Biology 1A – Lecture 31: Reproductive system-Part I
Biology 1A – Lecture 32
Biology 1A – Lecture 33:
Biology 1A – Lecture 34:
Biology 1A – Lecture 35:
Biology 1A – Lecture 36:
Biology 1A – Lecture 37:
Biology 1A – Lecture 38:
Biology 1A – Lecture 39:
Biology 1A – Lecture 40:
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Professors
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Sylvia Ceyer–Principles of Chemical Science–Massachusetts Institute of Technology Open Courseware–Videos
Victor Davis Hanson–Videos
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J. Michael McBride–Organic Chemistry–Yale University Online Course–Videos
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Read Full Post | Make a Comment ( None so far )Massive Budget Deficit Spending, National Debt and Tax Increases–Obama Successful Cloward-Piven Strategy–Over 30 Million Seek Jobs and Food Stamps or SNAP!
The Cloward/Piven Strategy 1
The Cloward/Piven Strategy 2
The Cloward/Piven Strategy 3
The Cloward/Piven Strategy 4
The Cloward/Piven Strategy 5
The Cloward/Piven Strategy 6
Background Articles and Videos
With health bill, Obama has sown the seeds of a budget crisis
“…Should the United States someday suffer a budget crisis, it will be hard not to conclude that Obama and his allies sowed the seeds, because they ignored conspicuous warnings. A further irony will not escape historians. For two years, Obama and members of Congress have angrily blamed the shortsightedness and selfishness of bankers and rating agencies for causing the recent financial crisis. The president and his supporters, historians will note, were equally shortsighted and self-centered — though their quest was for political glory, not financial gain.
Let’s be clear. A “budget crisis” is not some minor accounting exercise. It’s a wrenching political, social and economic upheaval. Large deficits and rising debt — the accumulation of past deficits — spook investors, leading to higher interest rates on government loans. The higher rates expand the budget deficit and further unnerve investors. To reverse this calamitous cycle, the government has to cut spending deeply or raise taxes sharply. Lower spending and higher taxes in turn depress the economy and lead to higher unemployment. Not pretty. …”
http://www.washingtonpost.com/wp-dyn/content/article/2010/03/28/AR2010032802353.html
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President Barack Obama’s Role Model–President Franklin D. Roosevelt–The Worse President For The U.S. and World Economies and The American People–With The Same Results–High Unemployment Rates–Over 25 Million American Citizens Seeking Full Time Jobs Today–Worse Than The Over 13 Million Seeking Jobs During The Worse of The Great Depression!
Progressives
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Obamanomics–New Deal Progressive Radical Socialist Interventionism
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Friedrich Hayek–Videos
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Peter Thiel–Videos
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American Citizens Want Jobs and Criminal Alien Removal, Not Criminal Alien Census and Health Care!
Broom Budget Busting Bums: Replace The Entire Congress–Tea Party Express and Patriots–United We Stand!
Discover The Left’s Organized Crime Network–Crime Pays–Organized Crimes Pays More–Apply for Census Taker Jobs!
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Glenn Beck – Friday March 26, 2010 – Part 1 of 4
Glenn Beck – Friday March 26, 2010 – Part 2 of 4
Glenn Beck – Friday March 26, 2010 – Part 3 of 4
Glenn Beck – Friday March 26, 2010 – Part 4 of 4
When the President of the United States insults the vast majority of the American people, they will remember his insults and ridicule in the next three elections.
President Obama is an educated fool and a self-absorbed narcissist whose protective bubble will burst when the cheers turn to boos.
Blaming everything on the past President, george W. Bush, will not work when the progressive radical socialist Democratic Party have controlled Congress since 2007 and the Presidency since 2009.
When the real unemployment rate is about 20% not the official rate of about 10% or 1 out of every 5 Americans is seeking a full time job, President Obama’s failed economic policies will rightly be blamed for extending the duration or time people are unemployed.
Results count.
No results on the jobs front, no votes come November in 2010 and 2012.
Glenn Beck forgets that with 30 million American citizens seeking jobs, the answer to the illegal immigration problem is comprehensive immigration law enforcement–the rule of law–not comprehensive immgration reform–social justice.
There are over 30 million illegal aliens living and working in the United States.
They are breaking the law and should be removed from their place of employment and with their families deported to their country of origin.
Rush got it right.
Rush Limbaugh on Illegal Immigration
Glenn I hope you are not going to sound like progressive radical socialist Nancy Pelosi on illegal aliens.
Pelosi says deporting illegal aliens is un-American
Glenn wake up and connect the dots.
Lou Dobbs With William Gheen 02-02-09
Immigration Gumballs Part 1/2
Immigration Gumballs Part 2/2
Stop Amnesty for Illegal Immigrants – Expert Reveals the True Cost of Amnesty
The Real Cost of Illegal Immigration
Stop Federal government spending by eliminating 10 Federal Departments.
Sell 90% of Federal government lands and let private companies explore and produce whatever natural resources are discovered on this real estate such as oil and natural gas.
Enact the FairTax to replace all Federal taxes.
Limit Federal Government spending to 80% of FairTax collections of the previous year.
Use the reminding 20% of FairTax revenues to pay off the National Debt.
Place both Social Security and Medicare on an acturial sound footing with individual ownershp of the account and control of investment amounts in the account as to where their money is invested.
Leave the United Nations and ask the United Nations to move to another country.
End the Federal Reserve System and fiat money and replace it with a gold/silver standard.
Let individuals purchase individual and family health insurance plans from any insurance company doing business in the United States and increase the annual amounts individuals can put into a Health Savings Account.
No more nation building abroad.
Bring all the troops home now.
Complete the border fence and have it heavily patrolled to stop all illegal immigration and drugssmuggling.
Remove illegal aliens from the workplace by using E-Verify.
Dep0rt illegal aliens to their country of origin.
Limit legal immigration to 250,000 immigrants per year.
Do away with anchor babies getting automatic citizenship.
Make English the official language of the country.
Accomplish all of the above by forming a new poltical party that would compete with both the Democratic and Republican parties and attract voters from the Democratic, Republican, Libertarian, and Conservative parties and would attract independents as well.
Start now and in twelve years all of the above would be accomplished.
Continue voting either Democratic or Republican and none of the above will ever happen.
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Background Articles and Videos
Donald Kagan
Donald Kagan (born 1932) is an American historian at Yale specializing in ancient Greece, notable for his four-volume history of the Peloponnesian War. He was Dean of Yale College from 1989–1992. He formerly taught in the Department of History at Cornell University. In a review in The New Yorker, critic George Steiner said of Kagan’s seminal four-volume history of the Peloponnesian War: “The temptation to acclaim Kagan’s four volumes as the foremost work of history produced in North America in this century is vivid.” Kagan is generally considered among the foremost scholars of Ancient Greek history at present.
Born into a Jewish family in Lithuania, Kagan grew up in the Brownsville section of Brooklyn, New York, where his family emigrated shortly after the death of his father. He graduated from Brooklyn College, then received an MA from Brown University and a PhD from the Ohio State University in 1958.[1]
Once a liberal Democrat, Professor Kagan changed his views by the 1970s and became one of the original signers to the 1997 Statement of Principles by the neoconservative think tank Project for the New American Century.[2] According to Jim Lobe, cited in The Fall Of The House Of Bush by Craig Unger (p.39, n.), Kagan’s turn away from liberalism occurred in the late sixties when Cornell University was pressured into starting a Black studies program by protesting students: “Watching administrators demonstrate all the courage of Neville Chamberlain had a great impact on me, and I became much more conservative.” On the eve of the 2000 presidential elections, Kagan and his son, Frederick Kagan, published While America Sleeps, a call to increase defense spending. The National Endowment for the Humanities (NEH) awarded Donald Kagan the National Humanities Medal in 2002, and selected him to deliver the 2005 Jefferson Lecture, which the NEH calls “the highest honor the federal government confers for distinguished intellectual achievement in the humanities.”[3] Kagan’s Jefferson Lecture was entitled “In Defense of History”;[4] he argued that history is of primary importance in the study of the humanities.[5][6]
Kagan is currently Sterling Professor of Classics and History at Yale University — a title reserved for only the select few most accomplished academics at Yale. His course “The Origins of War” was one of the university’s most popular courses for twenty-five years. He currently teaches “Introduction to Ancient Greek History” and upper level History and Classical Civilization seminars focusing on topics from Thucydides to Spartan Hegemony. He lives in New Haven, Connecticut.
Another son, Robert Kagan, is also active in conservative politics and foreign relations.
http://en.wikipedia.org/wiki/Donald_Kagan
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Background Articles and Videos
Edema
“…Edema (American English) or oedema (British English; both words from the Greek οἴδημα), formerly known as dropsy or hydropsy, is an abnormal accumulation of fluid beneath the skin or in one or more cavities of the body. Generally, the amount of interstitial fluid is determined by the balance of fluid homeostasis, and increased secretion of fluid into the interstitium or impaired removal of this fluid may cause edema.
Formation
Five factors can contribute to the formation of edema:
- It may be facilitated by increased hydrostatic pressure or,
- reduced oncotic pressure within blood vessels;
- by increased blood vessel wall permeability as in inflammation;
- by obstruction of fluid clearance via the lymphatic; or,
- by changes in the water retaining properties of the tissues themselves. Raised hydrostatic pressure often reflects retention of water and sodium by the kidney.[1]
Mechanism
Generation of interstitial fluid is regulated by the forces of the Starling equation.[2] Hydrostatic pressure within blood vessels tends to cause water to filter out into the tissue. This leads to a difference in protein concentration between blood plasma and tissue. As a result the oncotic pressure of the higher level of protein in the plasma tends to suck water back into the blood vessels from the tissue. Starling’s equation states that the rate of leakage of fluid is determined by the difference between the two forces and also by the permeability of the vessel wall to water, which determines the rate of flow for a given force imbalance. Most water leakage occurs in capillaries or post capillary venules, which have a semi-permeable membrane wall that allows water to pass more freely than protein. (The protein is said to be reflected and the efficiency of reflection is given by a reflection constant of up to 1.) If the gaps between the cells of the vessel wall open up then permeability to water is increased first, but as the gaps increase in size permeability to protein also increases with a fall in reflection coefficient.
Changes in the variables in Starling’s equation can contribute to the formation of edema either by an increase in hydrostatic pressure within the blood vessel, a decrease in the oncotic pressure within the blood vessel or an increase in vessel wall permeability. The latter has two effects. It allows water to flow more freely and it reduces the oncotic pressure difference by allowing protein to leave the vessel more easily.
Generalized edema
A rise in hydrostatic pressure occurs in cardiac failure. A fall in oncotic pressure occurs in nephrotic syndrome and liver failure. It is commonly thought that these facts explain the occurrence of edema in these conditions. However, it has been known since the 1950s that the situation is more complex and it is still far from completely understood.[3]
Causes of edema which are generalized to the whole body can cause edema in multiple organs and peripherally. For example, severe heart failure can cause pulmonary edema, pleural effusions, ascites and peripheral edema, the last of which effects can also derive from less serious causes.[4]
Although a low plasma oncotic pressure is widely cited for the edema of nephrotic syndrome, most physicians note that the edema may occur before there is any significant loss of protein in the urine or fall in plasma protein level. Fortunately there is another explanation available. Most forms of nephrotic syndrome are due to biochemical and structural changes in the basement membrane of capillaries in the kidney glomerulae, and these changes occur, if to a lesser degree, in the vessels of most other tissues of the body. Thus the resulting increase in permeability that leads to protein in the urine can explain the edema if all other vessels are more permeable as well.
Organ-specific edema
Edema will occur in specific organs as part of inflammation, as in pharyngitis, tendonitis or pancreatitis, for instance. Certain organs develop edema through tissue specific mechanisms.
Examples of edema in specific organs:
-
- Cerebral edema is extracellular fluid accumulation in the brain. It can occur in toxic or abnormal metabolic states and conditions such as systemic lupus. It causes drowsiness or loss of consciousness.
-
- Pulmonary edema occurs when the pressure in blood vessels in the lung is raised because of obstruction to removal of blood via the pulmonary veins. This is usually due to failure of the left ventricle of the heart. It can also occur in altitude sickness or on inhalation of toxic chemicals. Pulmonary edema produces shortness of breath. Pleural effusions may occur when fluid also accumulates in the pleural cavity.
-
- Edema may also be found in the cornea of the eye with glaucoma, severe conjunctivitis or keratitis or after surgery. It may produce coloured haloes around bright lights.
-
- Edema surrounding the eyes is called periorbital edema or eye puffiness. The periorbital tissues are most noticeably swollen immediately after waking, perhaps due to the gravitational redistribution of fluid in the horizontal position.
-
- Common appearances of cutaneous edema are observed with mosquito bites, spider bites, bee stings (wheal and flare), and skin contact with certain plants such as Poison Ivy or Western Poison Oak,[5] the latter of which are termed contact dermatitis.
-
- Another cutaneous form of edema is myxedema, which is caused by increased deposition of connective tissue. In myxedema (and a variety of other rarer conditions) edema is due to an increased tendency of the tissue to hold water within its extracellular space. In myxedema this is because of an increase in hydrophilic carbohydrate-rich molecules (perhaps mostly hyaluronan) deposited in the tissue matrix. Edema forms more easily in dependent areas in the elderly (sitting in chairs at home or on aeroplanes) and this is not well understood. Estrogens alter body weight in part through changes in tissue water content. There may be a variety of poorly understood situations in which transfer of water from tissue matrix to lymphatics is impaired because of changes in the hydrophilicity of the tissue or failure of the ‘wicking’ function of terminal lymphatic capillaries.
-
- In the case of human feet, the Starling forces are always a long way out of balance, because the variation in hydrostatic pressure in the vessels in the feet as compared to the face is about a metre of water. In severe heart failure the change in central venous pressure is tiny in comparison and cannot explain why edema of the feet develops simply through an effect on capillary leakage. Three other factors may be involved. If the central venous pressure rises to equal that of the thoracic lymph duct then clearance of fluid from the tissue will be impeded (see below). That is to say the edema may actually be caused by a change in output of fluid from the tissue, as much as input to the tissue. Secondly, severe heart failure is one of the most exhausting conditions there is. The sufferers tend to spend what little effort they can make trying to breathe with edematous lungs. They tend to sit up to make breathing easier and their feet hang immobile on the floor. Immobility is perhaps the commonest of all causes of edema, because clearance of fluid via the lymphatics needs muscle action. Thirdly, in severe heart failure endocrine and neural changes alter the way tissues are perfused in ways that are not fully understood.
-
- In lymphedema abnormal removal of interstitial fluid is caused by failure of the lymphatic system. This may be due to obstruction from, for example, pressure from a cancer or enlarged lymph nodes, destruction of lymph vessels by radiotherapy, or infiltration of the lymphatics by infection (such as elephantiasis). It is most commonly due to a failure of the pumping action of muscles due to immobility, most strikingly in conditions such as multiple sclerosis, or paraplegia. Lymphatic return of fluid is also dependent on a pumping action of structures known as lymph hearts. It has been suggested that the edema that occurs in some people following use of aspirin-like cyclo-oxygenase inhibitors such as ibuprofen or indomethacin may be due to inhibition of lymph heart action. …”
http://en.wikipedia.org/wiki/Edema
Capillaries
Capillaries (pronounced /ˈkæpəˌlɛri/) are the smallest of a body’s blood vessels and are part of the microcirculation. They are only 1 cell thick. These microvessels, measuring 5-10 μm in diameter, connect arterioles and venules, and enable the exchange of water, oxygen, carbon dioxide, and many other nutrient and waste chemical substances between blood and surrounding tissues.[1]
//
Anatomy
Blood flows from the heart to the arteries, which branch and narrow into the arterioles, and then branch further still into the capillaries. After the tissue has been perfused, capillaries join and widen to become venules and then widen more to become veins, which return blood to the heart.
The “capillary bed” is the network of capillaries supplying an organ. The more metabolically active the cells, the more capillaries they will require to supply nutrients and carry away waste products.
Metarterioles provide direct communication between arterioles and venules and are important in bypassing the bloodflow through the capillaries. True capillaries branch mainly from metarterioles and provide exchange between cells and the circulation. The internal diameter of 8 μm forces the red blood cells to partially fold into bullet-like shapes and to go into single file in order for them to pass through.
Precapillary sphincters are rings of smooth muscles at the origin of true capillaries that regulate blood flow into true capillaries and thus control blood flow through a tissue.
Types
There are three types of Capillaries:
- Continuous – Continuous capillaries have a sealed endothelium and only allow small molecules, like water and ions to diffuse. Continuous capillaries have tight junctions and can be further divided into two subtypes:
-
- Those with numerous transport vesicles that are primarily found in skeletal muscles, lungs, gonads, and skin.
- Those with few vesicles that are primarily found in the central nervous system. These capillaries are a constituent of the blood-brain-barrier.
- Fenestrated – Fenestrated capillaries (derived from “fenestra,” the Latin word for “window”) have pores in the endothelial cells (60-80 nm in diameter) that are spanned by a diaphragm of radially oriented fibrils and allow small molecules [2][3] and limited amounts of protein to diffuse. In the renal glomerulus there are larger fenestrae which have no diaphragms (although there are pedicels (podocyte foot processes) that have slit pores with an analogous function to the diaphragm of the capillaries). Both types of fenestrated blood vessels have continuous basal lamina and are primarily located in the endocrine glands, intestines, pancreas, and glomeruli of kidney.
- Sinusoidal – Sinusoidal or discontinuous capillaries are special fenestrated capillaries that have larger openings (30-40 μm in diameter) in the endothelium to allow red and white blood cells (7.5μm – 25μm diameter) and various serum proteins to pass, a process that is aided by a discontinuous basal lamina. These capillaries lack pinocytotic vesicles and gaps may be present in cell junctions permitting leakage between endothelial cells. Sinusoid blood vessels are primarily located in the liver, spleen, bone marrow, lymph nodes, and adrenal gland.
The membrane in the capillary is only 1 cell thick and is squamous epithelium.
Physiology
The capillary wall is a one-layer endothelium that allows gas and lipophilic molecules to pass through without the need for special transport mechanisms. This transport mechanism allows bidirectional diffusion depending on osmotic gradients and is further explained by the Starling equation.
Capillary beds may control their blood flow via autoregulation. This allows an organ to maintain constant flow despite a change in central blood pressure. This is achieved by myogenic response and in the kidney by tubuloglomerular feedback. When blood pressure increases the arterioles that lead to the capillaries bed are stretched and subsequently constrict to counteract the increased tendency for high pressure to increase blood flow. In the lungs special mechanisms have been adapted to meet the needs of increased necessity of blood flow during exercise. When the heart rate increases and more blood must flow through the lungs capillaries are recruited and are also distended to make room for increased blood flow. This allows blood flow to increase while resistance decreases.
Capillary permeability can be increased by the release of certain cytokines, anaphylatoxins, or other mediators (such as leukotrienes, prostaglandins, histamine, bradykinin, etc.) highly influenced by the immune system.
The Starling equation defines the forces across a semipermeable membrane and allows calculation of the net flux:
where:
- ([Pc − Pi] − σ[πc − πi]) is the net driving force,
- Kf is the proportionality constant, and
- Jv is the net fluid movement between compartments.
By convention, outward force is defined as positive, and inward force is defined as negative. The solution to the equation is known as the net filtration or net fluid movement (Jv). If positive, fluid will tend to leave the capillary (filtration). If negative, fluid will tend to enter the capillary (absorption). This equation has a number of important physiologic implications, especially when pathologic processes grossly alter one or more of the variables.
The variables
According to Starling’s equation, the movement of fluid depends on six variables:
- Capillary hydrostatic pressure ( Pc )
- Interstitial hydrostatic pressure ( Pi )
- Capillary oncotic pressure ( πz )
- Interstitial oncotic pressure ( πi )
- Filtration coefficient ( Kf )
- Reflection coefficient ( σ )
- Note that oncotic pressure is not illustrated in the image.
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Freshman Organic Chemistry with J. Michael McBride
This is the first semester in a two-semester introductory course focused on current theories of structure and mechanism in organic chemistry, their historical development, and their basis in experimental observation. The course is open to freshmen with excellent preparation in chemistry and physics, and it aims to develop both taste for original science and intellectual skills necessary for creative research.
Syllabus
Professor:
J. Michael McBride, Richard M. Colgate Professor of Chemistry, Yale University
Description:
This is the first semester in a two-semester introductory course focused on current theories of structure and mechanism in organic chemistry, their historical development, and their basis in experimental observation. The course is open to freshmen with excellent preparation in chemistry and physics, and it aims to develop both taste for original science and intellectual skills necessary for creative research.
Texts:
Reading assignments, problem sets, PowerPoint presentations, and other resources for this course can be accessed from Professor McBride’s on-campus course website, which was developed for his Fall 2008 students. Please see Resources section for each individual lecture.
Requirements:
The course grade is based on a 650-point system: 100 points for each of the three hour-long midterm examinations, 300 points for the three-hour final examination, and 50 points for participation in the course Wiki. In borderline cases, faithfulness in completing and submitting problem sets will be considered.
Grading:
Midterm Examination 1: 100 points
Midterm Examination 2: 100 points
CHEM 125: Freshman Organic Chemistry
Class Sessions
Click session titles below to access audio, video, and course materials.
1. How Do You Know?
2. Force Laws, Lewis Structures and Resonance
3. Double Minima, Earnshaw’s Theorem and Plum-Puddings
4. Coping with Smallness and Scanning Probe Microscopy
5. X-Ray Diffraction
6. Seeing Bonds by Electron Difference Density
7. Quantum Mechanical Kinetic Energy
8. One-Dimensional Wave Functions
9. Chladni Figures and One-Electron Atoms
10. Reality and the Orbital Approximation
11. Orbital Correction and Plum-Pudding Molecules
12. Overlap and Atom-Pair Bonds
13. Overlap and Energy-Match
14. Checking Hybridization Theory with XH_3
15. Chemical Reactivity: SOMO, HOMO, and LUMO
16. Recognizing Functional Groups
17. Reaction Analogies and Carbonyl Reactivity
18. Amide, Carboxylic Acid and Alkyl Lithium
19. Oxygen and the Chemical Revolution (Beginning to 1789)
20. Rise of the Atomic Theory (1790-1805)
21. Berzelius to Liebig and Wöhler (1805-1832)
22. Radical and Type Theories (1832-1850)
23. Valence Theory and Constitutional Structure (1858)
24. Determining Chemical Structure by Isomer Counting (1869)
25. Models in 3D Space (1869-1877); Optical Isomers
26. Van’t Hoff’s Tetrahedral Carbon and Chirality
27. Communicating Molecular Structure in Diagrams and Words
28. Stereochemical Nomenclature; Racemization and Resolution
29. Preparing Single Enantiomers and the Mechanism of Optical Rotation
30. Esomeprazole as an Example of Drug Testing and Usage
31. Preparing Single Enantiomers and Conformational Energy
32. Stereotopicity and Baeyer Strain Theory
33. Conformational Energy and Molecular Mechanics
34. Sharpless Oxidation Catalysts and the Conformation of Cycloalkanes
35. Understanding Molecular Structure and Energy through Standard Bonds
36. Bond Energies, the Boltzmann Factor and Entropy
37. Potential Energy Surfaces, Transition State Theory and Reaction Mechanism
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5.112 Principles of Chemical Science
As taught in: Fall 2005
Level:
Instructors:
Prof. Sylvia Ceyer
Prof. Christopher Cummins
Course Features
Course Highlights
Course Description
Technical Requirements
Special software is required to use some of the files in this course: .iv, .rm, and .mp3.
Syllabus
Help support MIT OpenCourseWare by shopping at Amazon.com! MIT OpenCourseWare offers direct links to Amazon.com to purchase the books cited in this course. Click on the Amazon logo to the left of any citation and purchase the book from Amazon.com, and MIT OpenCourseWare will receive up to 10% of all purchases you make. Your support will enable MIT to continue offering open access to MIT courses. |
Textbooks
Atkins, Peter and Loretta Jones. Chemical Principles: The Quest for Insight. 3rd ed. New York, NY: W.H. Freeman and Company, 2004. ISBN: 9780716757016.
———. Chemical Principles: The Quest for Insight/Student Study Guide and Solutions Manual. 3rd ed. New York, NY: W.H. Freeman and Company, 2004. ISBN: 9780716707400. (Bundled set. ISBN: 9780716762546.)
Grading
activities | points |
---|---|
Three 1-hour Exams (100 points each) | 300 |
Final Exam | 300 |
Homework | 100 |
Total | 700 |
Readings
Help support MIT OpenCourseWare by shopping at Amazon.com! MIT OpenCourseWare offers direct links to Amazon.com to purchase the books cited in this course. Click on the Amazon logo to the left of any citation and purchase the book from Amazon.com, and MIT OpenCourseWare will receive up to 10% of all purchases you make. Your support will enable MIT to continue offering open access to MIT courses. |
Readings are from the required textbook:
Atkins, Peter and Loretta Jones. Chemical Principles: The Quest for Insight. 3rd ed. New York, NY: W.H. Freeman and Company, 2004. ISBN: 9780716757016.
Lec # | Topics | readings |
---|---|---|
Review of High School Chemistry Topics | FundamentalsSection A.1Sections B.3-B.5
Sections C – M Sections 1.A – 1.F Sections 2.4 – 2.12 Sections 3.1 – 3.3 Sections 6.14 – 6.21 |
|
1-5 | Atomic Theory of MatterDiscovery of NucleusWave-Particle Duality of Radiation and Matter
Particle-Like Nature of Light Matter as a Wave |
Sections A.2 – A.3Sections B.1 – B.2Sections 1.1 – 1.7 |
6-8 | Schrödinger Equation for H AtomHydrogen Atom WavefunctionsP Orbitals | Sections 1.8 – 1.10 |
9-13 | Electronic Structure of Multielectron AtomsPeriodic Trends in Elemental PropertiesWhy Wavefunctions are Important?
Ionic Bonds – Classical Model and Mechanism Kinetic Theory – Behavior of Gases |
Sections 1.11 – 1.21Section 2.3Sections 2.14 – 2.17
Sections 4.13 – 4.15 |
14 | Distribution Molecular Energies | Sections 13.11 – 13.13 |
15-18 | Internal Degrees of FreedomIntermolecular InteractionsPolarizability
Thermodynamics and Spontaneous Change |
Chapter 2, Box 2.2, p. 77.Chapter 5, Sections 5.1 – 5.5Chapter 6, Sections 6.3, 6.6, 6.7, 6.14, 6.16 – 6.19, and 6.21
Chapter 7, Sections 7.1 – 7.2, 7.8, 7.11-7.13, and 7.15 Chapter 9 |
19 | Molecular Description of Acids and Bases | |
20 | Lewis and Brønsted Acid-Base Concepts | |
21 | Titration Curves and pH Indicators | |
22 | Electrons in Chemistry: Redox Processes | |
23 | Cell Potentials and Free Energy | |
24 | Theory of Molecular Shapes | |
25 | Valence Bond Theory | |
26 | Molecular Orbital Theory | |
27 | Molecular Orbital Theory for Diatomic Molecules | |
28 | Molecular Orbital Theory for Polyatomic Molecules | |
29-30 | Crystal Field Theory | |
31 | Color and Magnetism of Coordination Complexes | |
32 | Coordination Complexes and Ligands | |
33 | Ligand Substitution Reactions: Kinetics | |
34 | Bonding in Metals and Semiconductors | |
35 | Metals in Biology | |
36 | Nuclear Chemistry and the Cardiolite® Story |
http://ocw.mit.edu/OcwWeb/Chemistry/5-112Fall-2005/VideoLectures/detail/embed01.htm
http://www.youtube.com/user/MIT
Lecture 1: Atomic Theory of Matter
Lecture 2: Discovery of Nucleus
Lecture 3: Wave-Particle Duality of Radiation and Matter
Lecture 4: Particle-Like Nature of Light
Lecture 5: Matter as a Wave
Lecture 6: Schrodinger Equation for H Atom
Lecture 7:Hydrogen Atom Wave functions
Lecture 8: P Orbitals
Lecture 9: Electronic Structure of Multi-electron Atoms
Lecture 10: Periodic Trends in Elemental Properties
Lecture 11: Why Wavefunctions are Important?
Lecture 12: Ionic Bonds – Classical Model and Mechanism
Lecture 13: Kinetic Theory – Behavior of Gases
Lecture 14: Distribution Molecular Energies
Lecture 15: Internal Degrees of Freedom
Lecture 16: Intermolecular Interactions
Lecture 17: Polarizability
Lecture 18: Thermodynamics and Spontaneous Change
Lecture 19: Molecular Description of Acids and Bases
Lecture 20: Lewis and Bronsted Acid-Base Concepts
Lecture 21:Titration Curves and pH Indicators
Lecture 22: Electrons in Chemistry: Redox Processes
Lecture 23: Cell Potentials and Free Energy
Lecture 24: Theory of Molecular Shapes
Lecture 25: Valence Bond Theory
Lecture 26: Molecular Orbital Theory
Lecture 27: Molecular Orbital Theory for Diatomic Molecules
Lecture 28: Molecular Orbital Theory for Polyatomic Molecules
Lecture 29: Crystal Field Theory
Lecture 30: Crystal Field Theory View
Lecture 31: Color and Magnetism of Coordination Complexes
Lecture 32: Coordination Complexes and Ligands
Lecture 33: Ligand Substitution Reactions: Kinetics
Lecture 34: Bonding in Metals and Semiconductors
Lecture 35: Nuclear Chemistry and the Cardiolite(R) Story
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Kaye won a Golden Globe Award for Best Actor in a Motion Picture Musical or Comedy for his portrayal of Jacobowsky, the refugee.
During the invasion of France by Nazi Germany, a shy, intelligent Jewish refugee tries to flee from the Nazis with the aid of an anti-Semitic, autocratic, brave Polish Colonel who is trying to smuggle papers to England. Their dysfunctional partnership is made even more difficult when both men begin to fall in love with the same French innkeeper’s daughter — the Colonel’s fiancee.
The film uses the contrasting characters of the Jacobowsky and Prokoszny to examine their world views. Jacobowsky is timid, intelligent and creative, where Prokoszny is brave, rash, and stuck in his ways. The movie has Prokoszny gradually embracing the viewpoint of the very different S. L. Jacobowsky, quoting his mother, that “In life, there are always two possibilities.” …”
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Me and The Colonel
“…Me and the Colonel is a 1958 film based on the play “Jacobowsky und der Oberst” by Franz Werfel. It was directed by Peter Glenville and stars Danny Kaye, Curd Jürgens and Akim Tamiroff.
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During the invasion of France by Nazi Germany, a shy, intelligent Jewish refugee tries to flee from the Nazis with the aid of an anti-Semitic, autocratic, brave Polish Colonel who is trying to smuggle papers to England. Their dysfunctional partnership is made even more difficult when both men begin to fall in love with the same French innkeeper’s daughter — the Colonel’s fiancee.
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